Hunan Yotai Heavy Industry has made a major breakthrough in the research field of phosphogypsum filling technology

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2022-12-10

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Hunan Yotai Heavy Industry Co., Ltd. has made a major breakthrough in the field of phosphogypsum filling technology research.

The utilization rate of phosphogypsum in China is less than 40%, the stock of phosphogypsum has now exceeded 0.3 billion tons, and nearly 100 phosphogypsum storage yards are in use. It not only takes up a lot of land, but also poses a potential threat to the environment. How to treat and use phosphogypsum efficiently and safely is an urgent problem to be solved.

In 2003, Kailin Group first proposed the reuse method of phosphogypsum as aggregate to fill underground goaf, that is, the total phosphorus slag self-cementing filling mining technology of acidic ultra-fine phosphogypsum waste as filling aggregate and yellow phosphorus slag instead of cement. However, various heavy metals exist in different forms under the mine, and some heavy metals such as arsenic, manganese and zinc have high acid soluble content and need long-term monitoring.

Hemihydrate phosphogypsum is a by-product of hemihydrate phosphoric acid process phosphogypsum, the main component is CaSO4 · 1/2H2O, because it contains only half of the crystal water, with potential gelling activity, but by phosphorus, fluorine and other impurities and crystalline form, it is not like building gypsum powder with gelling, need to be modified to form strength.

Hunan Yutai Heavy Industry Co., Ltd. has actively organized research and development teams since the EPC project of Guizhou Batian Ecological Engineering Co., Ltd. in early 2022. Through theoretical research, experimental research and industrial research, hemihydrate phosphogypsum is added with water, washed and dehydrated, heated to a certain temperature, then rapidly cooled, ground into fine powder and added a certain proportion of yellow phosphorus slag powder, lime powder, fly ash, a small amount of additives, prepared into semi-water phosphorus gypsum modified cementitious materials. It can replace cement in mine filling and be applied to mine filling. The filling body made of this material has the characteristics of high strength, low cost, safety and reliability (no toxic gas is produced in the filling process), low bleeding rate (<3%), etc., so as to achieve the purpose of "one waste and two harms.

 

The breakthrough of hemihydrate phosphogypsum modified cementing material and filling technology has successfully solved the two major problems of phosphogypsum storage in phosphorus chemical enterprises and high filling cost in phosphorus mining enterprises, which can greatly improve the mine recovery rate and the large-scale utilization of phosphogypsum. The effect of cost reduction and efficiency increase is outstanding, which is of great significance to the construction of green mines and the transformation and upgrading of phosphorus chemical industry, and has significant economic and social benefits.

Hunan Yutai Heavy Industry Co., Ltd. was established in 2012 with a registered capital of 50 million yuan. Its products include complete sets of tailings filling equipment, filling industrial pumps, deep cone thickener, high-efficiency mixing tank, filling automatic control system and concrete pump. It has obtained more than 20 national patents and passed the ISO9001 quality system certification. It is a high-tech enterprise supported by Ningxiang City and has been recommend by CCTV as a Chinese national brand of mining machinery.

The company integrates R & D, production, sales and project operation, deeply cultivates products and researches technology, which has been recognized by a large number of users and friends, and has become a qualified supplier of many central enterprises and large private enterprises. The company has a professional R & D and after-sales service technical team, with a passionate "professional, dedicated, caring" work attitude, to provide users with high quality, cost-effective products and services.

 

Hunan Yutai Heavy Industry Co., Ltd.

12 years focused on mine filling complete sets of equipment

Contact number: 18774995599

Website: www.yotaihn.com

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